Watching metal nanoparticle exsolution

5. Myrmekite Formed by Exsolution?

At the first site, the Weinsberg (Moldanubian) granite and an older quartzmonzonite facies of the South Bohemian pluton in Austria both contain orthopyroxene and clinopyroxene and must have crystallized from magmas at high temperatures. The granite contains orthoclase megacrysts (as much as 10 to 20 cm long), which (1) are chemically zoned with Ba-rich cores (1 to 2 % mol Cs; and locally as muc...

Evidence and Model for Strain-Driven Release of Metal Nanocatalysts from Perovskites during Exsolution.

The evolution of the surface morphology during exsolution of Ni from the perovskite La0.4Sr0.4Ti0.97Ni0.03O3-δ under reducing conditions was determined using atomic force microscopy. The exsolution process was found to initially induce the formation of a 20-30 nm deep pit on the oxide surface followed by the emergence of a Ni particle at the bottom of the pit. Continued emergence of the particl...

metal nanoparticle production assisted by α-amylase

Metal nanoparticle catalysts decorated with metal oxide clusters.

Au nanoparticles decorated with mononuclear Ti-oxo units dispersed in silica clusters were formed by activating Au nanoparticles (~2 nm) stabilized with Ti- and amine-functionalized siloxane oligomers. These Au nanoparticles were active catalysts for selective oxidation of propane to acetone, and the activity increased with increasing Ti density.

Bioinspired Metal Nanoparticle: Synthesis, Properties and Application

Nanomaterials with a characteristic dimension in the range of 1-100 nanometers (nm) are at the leading edge of nanoscience and nanotechnology. In recent years nanomaterials, and specifically metal nanoparticles, have received particular interest in diverse field ranging from material science to biotechnology (Guo et al. 2005, Daniel and Astruc 2004, Huang et al. 2007). Although widespread inter...